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The Regional Stream Water Geochemical Mapping data set gives information on the elemental concentrations in organic sediments of small headwater streams. The samples have been taken from small headwater streams (catchment area under 30 km2) in the late summer of 1990. Sampling has been repeated for about every fourth point during the years 1995, 2000 and 2006. The number of samples was 1162 in 1990 (at a density of one sample / 300 km2), 286 in 1995, 286 in 2000 and 249 in 2006. The data set covers the whole of Finland. Stream water samples have also been taken at the same time. Sampling, processing and analysis methods have been described in the Geochemical Atlas of Finland, Part 3, p. 27 - 30 (Lahermo et. al 1996). Field observations, coordinates and element concentrations determined from samples have been made into a database, in which each record represents one sample point. The data for each sampling year have been recorded on different tables. The method of analysis is referred to with a four-character method code. The codes are as follows: 503H = mercury determination using the cold vapour method 503P = nitric acid extraction in a microwave oven, measurement with ICP-AES 503M = nitric acid extraction in a microwave oven, measurement with ICP-MS 820L = carbon, hydrogen and nitrogen determination with a LECO analyser. The element concentration data include a numerical concentration value (as mg kg-1 or ppm) and possibly a check mark. The concentration is recorded as a variable, which has a name that comprises the chemical symbol for the element and the code for the method of analysis. For example AS_503M is arsenic (As) concentration, which is determined with the ICP-MS method (503M). The next variable has a check mark, for example AS_503MT. If the numerical value following the check mark is ‘>’ or '‘<’ then the number recorded in the concentration field is the determination limit of the chemical analytical method used and the actual concentration is less than this value. If the check mark is an exclamation mark (!), the analytical result is smaller than the determination limit of the analytical method use but the (unreliable) value obtained with the measuring instrument has been entered in the database. There is no data are if the check mark is a 'x'. The original purpose of the Regional Stream Water Geochemical Mapping data set was national general geochemical mapping and the basic assessment of environmental state. Other uses are, for example, the assessment of changes in environmental state and determination of the baseline concentrations of surface water as part of the evaluation of the chemical state of catchment areas in accordance with the Water Framework Directive of the EU.
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The Regional Stream Sediment Geochemical Mapping data set gives information on the elemental concentrations in organic sediments of small headwater streams. The samples have been taken from small headwater streams (catchment area under 30 km2) in the late summer of 1990. Sampling has been repeated for about every fourth point during the years 1995, 2000 and 2006. The number of samples was 1162 in 1990 (at a density of one sample / 300 km2), 286 in 1995, 286 in 2000 and 249 in 2006. The data set covers the whole of Finland. Stream water samples have also been taken at the same time. Sampling, processing and analysis methods have been described in the Geochemical Atlas of Finland, Part 3, p. 27 - 30 (Lahermo et. al 1996). Field observations, coordinates and element concentrations determined from samples have been made into a database, in which each record represents one sample point. The data for each sampling year have been recorded on different tables. The method of analysis is referred to with a four-character method code. The codes are as follows: 503H = mercury determination using the cold vapour method 503P = nitric acid extraction in a microwave oven, measurement with ICP-AES 503M = nitric acid extraction in a microwave oven, measurement with ICP-MS 820L = carbon, hydrogen and nitrogen determination with a LECO analyser. The element concentration data include a numerical concentration value (as mg kg-1 or ppm) and possibly a check mark. The concentration is recorded as a variable, which has a name that comprises the chemical symbol for the element and the code for the method of analysis. For example AS_503M is arsenic (As) concentration, which is determined with the ICP-MS method (503M). The next variable has a check mark, for example AS_503MT. If the numerical value following the check mark is ‘>’ or '‘<’ then the number recorded in the concentration field is the determination limit of the chemical analytical method used and the actual concentration is less than this value. If the check mark is an exclamation mark (!), the analytical result is smaller than the determination limit of the analytical method use but the (unreliable) value obtained with the measuring instrument has been entered in the database. There is no data are if the check mark is a 'x'. The original purpose of the Regional Stream Water Geochemical Mapping data set was national general geochemical mapping and the basic assessment of environmental state. Other uses are, for example, the assessment of changes in environmental state and determination of the baseline concentrations of surface water as part of the evaluation of the chemical state of catchment areas in accordance with the Water Framework Directive of the EU. The original purpose of the Regional Stream Water Geochemical Mapping data set was national general geochemical mapping and the basic assessment of environmental state. Other uses are, for example, the assessment of changes in environmental state and determination of the baseline concentrations of surface water as part of the evaluation of the chemical state of catchment areas in accordance with the Water Framework Directive of the EU.
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The Regional Till Geochemical Mapping data set gives information on the concentrations of 37 elements in unaltered basal till. The samples have been taken, in 1983, from an unaltered basal till (C horizon) below the groundwater table at a depth of ca. 70 cm (variation 50-200 cm) with a density of one sample per 300 km2. The data set covers the whole of Finland with a total sample amount of 1056. The samples are composite field samples. The calculated sample point coordinates entered in the data set have been obtained from the centroid coordinates of five subsamples. The subsamples have been collected from a 300 m x 1000 m rectangular-shaped area. In Northern Finland, samples have been obtained by including samples taken previously in the Nordkallot Project. The samples have been sieved for analysis at a grain size grade less than 0.06 mm. The samples have been analysed for total elemental concentrations and aqua regia concentrations. Total concentrations have been determined either by neutron activation analysis (method code 900N) or by total dissolution with strong concentrated mineral acids (method code 312P). The analysis code for aqua regia dissolution is 511P. Gold and palladium have been determined with a analysis method based on flameless atomic absorption (519U). The sulfur concentration has been determined with a LECO analyser (810L). Further, total concentrations (312P) and aqua regia soluble concentrations (511P) were determined from Southern Finland and Mid-Finland samples with a grain size grade less than two millimetres. The original purpose of the Regional Till Geochemical Mapping data set was national geochemical general mapping and ore exploration. Other uses are, for example, estimating the baseline concentration of the soil, the nutrient levels of forest soil, assessing the buffering capacity of base cations in the soil and evaluating the weathering rate.